(2,6-Bis{1-[4-(dimethyl-amino)phenyl-imino]eth-yl}-pyridine) -dichlorido-(tri-phenyl-phosphine-P)ruthenium(II): a zigzag chain of fused centrosymmetric R2 2(12) rings
dc.contributor.author | Özdemir N. | |
dc.contributor.author | Dinçer M. | |
dc.contributor.author | Dayan O. | |
dc.contributor.author | Çetinkaya B. | |
dc.date.accessioned | 2019-10-27T08:37:37Z | |
dc.date.available | 2019-10-27T08:37:37Z | |
dc.date.issued | 2007 | |
dc.department | Ege Üniversitesi | en_US |
dc.description.abstract | The title compound, [RuCl2(C25H29N5)(C18H15P)], a transfer hydrogenation catalyst, is supported by an N,N',N''-tridentate pyridine-bridged ligand and triphenyl-phosphine. The RuII centre is six-coordinated in a distorted octa-hedral arrangement, with the two Cl atoms located in the axial positions, and the pyridine (py) N atom, the two imino N atoms and the triphenyl-phosphine P atom located in the equatorial plane. The two equatorial Ru - Nimino distances (mean 2.093 Å) are substantially longer than the equatorial Ru - Npy bond [1.954 (4) Å]. It is observed that the Nimino - M - Npy bond angle for the five-membered chelate rings of 2,6-bis(imino)pyridine-based complexes is inversely related to the magnitude of the M - Npy bond. The title structure is stabilized by intra- and inter-molecular C - H?Cl hydrogen bonds, as well as by intra-molecular ?-? stacking inter-actions between the aromatic rings belonging to the triphenyl-phosphine ligand and the dimethyl-amino-phenyl fragment. The inter-molecular hydrogen bonds form an R 2 2(12) ring and a zigzag chain of fused centrosymmetric rings running parallel to the [100] direction. © International Union of Crystallography 2007. | en_US |
dc.identifier.doi | 10.1107/S0108270107021610 | |
dc.identifier.endpage | m266 | en_US |
dc.identifier.issn | 0108-2701 | |
dc.identifier.issn | 0108-2701 | en_US |
dc.identifier.issue | 6 | en_US |
dc.identifier.scopusquality | N/A | en_US |
dc.identifier.startpage | m264 | en_US |
dc.identifier.uri | https://doi.org/10.1107/S0108270107021610 | |
dc.identifier.uri | https://hdl.handle.net/11454/27551 | |
dc.identifier.volume | 63 | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.relation.ispartof | Acta Crystallographica Section C: Crystal Structure Communications | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.title | (2,6-Bis{1-[4-(dimethyl-amino)phenyl-imino]eth-yl}-pyridine) -dichlorido-(tri-phenyl-phosphine-P)ruthenium(II): a zigzag chain of fused centrosymmetric R2 2(12) rings | en_US |
dc.type | Article | en_US |