Syntheses and properties of metal containing polyimides based on the gold carbene complex

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dc.contributor.authorSeckin, T
dc.contributor.authorKoytepe, S
dc.contributor.authorOzdemir, I
dc.contributor.authorCetinkaya, B
dc.date.accessioned2019-10-27T19:01:38Z
dc.date.available2019-10-27T19:01:38Z
dc.date.issued2003
dc.departmentEge Üniversitesien_US
dc.description.abstractA novel gold carbene complex, bis(1,3-di-p-dimethylaminobenzylimidazolidinylidene) gold(I), was synthesized and polymerized to polyimides in a one-step method with various aromatic dianhyrides. The gold-coordinated polyimides are characterized by IR and NMR (H-1, C-13) spectroscopy. The materials have inherent viscosities that range from 1.88 to 2.39 dl/g and show excellent solubility in N-methylpyrrolidone and N,N-dimethylacetamide. The glass transition temperatures of the coordinated polyimides range from 203-265degreesC and a 5% weight loss in air is observed from 535-578degreesC. The polymers form dark yellow, tough films that are transparent above 365 nm. The effect of different flexible units on the properties of the polyimides is discussed.en_US
dc.identifier.doi10.1023/A:1022905015133
dc.identifier.endpage20en_US
dc.identifier.issn1053-0495
dc.identifier.issn1053-0495en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage9en_US
dc.identifier.urihttps://doi.org/10.1023/A:1022905015133
dc.identifier.urihttps://hdl.handle.net/11454/37920
dc.identifier.volume13en_US
dc.identifier.wosWOS:000181795300002en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherKluwer Academic/Plenum Publen_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectpolyimideen_US
dc.subjectgold(I) coordinated polyimidesen_US
dc.subjectorganometallic polymeren_US
dc.subjectcarbene complexesen_US
dc.titleSyntheses and properties of metal containing polyimides based on the gold carbene complexen_US
dc.typeArticleen_US

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