Investigation of Photochemical Reactions of some Metal Carbonyls with ?-(2-Hydroxy-6-Methylbenzylidene)Methanesulfonohydrazide and 5-Methyl-2-Hydroxyacetophenonemethanesulfonylhydrazone

dc.authorscopusid7003673837
dc.contributor.authorSert S.
dc.date.accessioned2023-01-12T20:23:57Z
dc.date.available2023-01-12T20:23:57Z
dc.date.issued2021
dc.departmentN/A/Departmenten_US
dc.description.abstractEight new complexes, [M(CO)5(5msalmsh)] [M=Cr;(1a), Mo;(2a); W(3a)], [Re(CO)4Br(5msalmsh)] (4a), [M(CO)5(5mafmsh)] [M=Cr;(1b), Mo;(2b); W(3b)], [Re(CO)4Br(5mafmsh)] (4b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO)6] (M=Cr, Mo, W) and [Re(CO)5Br] with ?-(2-Hydroxy-6-Methylbenzylidene) Methanesulfonohydrazide (5msalmsh) and 5-methyl-2-hydroxyacetophenonemethanesulfonylhydrazone (5mafmsh). The complexes have been characterized by elemental analysis, LC-MS, FT-IR, 1H NMR spectroscopy. Spectroscopic studies show that 5msalmsh and 5mafmsh behave monodentate ligand and coordinate via an imine N donor atom to the central metal atom in (1a) (4a) and (1b) (4b). © 2021 Slovensko Kemijsko Drustvo. All rights reserved.en_US
dc.identifier.doi10.17344/ACSI.2019.5249
dc.identifier.endpage487en_US
dc.identifier.issn13180207
dc.identifier.issn1318-0207en_US
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85108329333en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage483en_US
dc.identifier.urihttps://doi.org/10.17344/ACSI.2019.5249
dc.identifier.urihttps://hdl.handle.net/11454/79797
dc.identifier.volume68en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSlovensko Kemijsko Drustvoen_US
dc.relation.ispartofActa Chimica Slovenicaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectHydrazonesen_US
dc.subjectmetal carbonylsen_US
dc.subjectmonodentate ligandsen_US
dc.subjectphotochemical reactions.en_US
dc.titleInvestigation of Photochemical Reactions of some Metal Carbonyls with ?-(2-Hydroxy-6-Methylbenzylidene)Methanesulfonohydrazide and 5-Methyl-2-Hydroxyacetophenonemethanesulfonylhydrazoneen_US
dc.typeArticleen_US

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