Investigation of Photochemical Reactions of some Metal Carbonyls with ?-(2-Hydroxy-6-Methylbenzylidene)Methanesulfonohydrazide and 5-Methyl-2-Hydroxyacetophenonemethanesulfonylhydrazone
dc.authorscopusid | 7003673837 | |
dc.contributor.author | Sert S. | |
dc.date.accessioned | 2023-01-12T20:23:57Z | |
dc.date.available | 2023-01-12T20:23:57Z | |
dc.date.issued | 2021 | |
dc.department | N/A/Department | en_US |
dc.description.abstract | Eight new complexes, [M(CO)5(5msalmsh)] [M=Cr;(1a), Mo;(2a); W(3a)], [Re(CO)4Br(5msalmsh)] (4a), [M(CO)5(5mafmsh)] [M=Cr;(1b), Mo;(2b); W(3b)], [Re(CO)4Br(5mafmsh)] (4b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO)6] (M=Cr, Mo, W) and [Re(CO)5Br] with ?-(2-Hydroxy-6-Methylbenzylidene) Methanesulfonohydrazide (5msalmsh) and 5-methyl-2-hydroxyacetophenonemethanesulfonylhydrazone (5mafmsh). The complexes have been characterized by elemental analysis, LC-MS, FT-IR, 1H NMR spectroscopy. Spectroscopic studies show that 5msalmsh and 5mafmsh behave monodentate ligand and coordinate via an imine N donor atom to the central metal atom in (1a) (4a) and (1b) (4b). © 2021 Slovensko Kemijsko Drustvo. All rights reserved. | en_US |
dc.identifier.doi | 10.17344/ACSI.2019.5249 | |
dc.identifier.endpage | 487 | en_US |
dc.identifier.issn | 13180207 | |
dc.identifier.issn | 1318-0207 | en_US |
dc.identifier.issue | 2 | en_US |
dc.identifier.scopus | 2-s2.0-85108329333 | en_US |
dc.identifier.scopusquality | Q3 | en_US |
dc.identifier.startpage | 483 | en_US |
dc.identifier.uri | https://doi.org/10.17344/ACSI.2019.5249 | |
dc.identifier.uri | https://hdl.handle.net/11454/79797 | |
dc.identifier.volume | 68 | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Slovensko Kemijsko Drustvo | en_US |
dc.relation.ispartof | Acta Chimica Slovenica | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Hydrazones | en_US |
dc.subject | metal carbonyls | en_US |
dc.subject | monodentate ligands | en_US |
dc.subject | photochemical reactions. | en_US |
dc.title | Investigation of Photochemical Reactions of some Metal Carbonyls with ?-(2-Hydroxy-6-Methylbenzylidene)Methanesulfonohydrazide and 5-Methyl-2-Hydroxyacetophenonemethanesulfonylhydrazone | en_US |
dc.type | Article | en_US |