Utilization of coordinating green solvents for high quality methylammonium bismuth iodide thin films for photovoltaic applications

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dc.authoridYesil, Tamer/0000-0003-4640-3158
dc.authorscopusid56996979900
dc.authorscopusid57216489633
dc.authorscopusid8379291000
dc.contributor.authorMutlu, Adem
dc.contributor.authorYesil, Tamer
dc.contributor.authorZafer, Ceylan
dc.date.accessioned2023-01-12T19:56:03Z
dc.date.available2023-01-12T19:56:03Z
dc.date.issued2021
dc.departmentN/A/Departmenten_US
dc.description.abstractPhotovoltaic performances of the bismuth-based solar cells are profoundly affected by the thin film quality of the photoactive layer. Herein, we report on various green solvent system to obtain the highly crystalline, pinhole free and homogeneously methylammonium bismuth iodide (MBI) active layer. The MBI structure prepared with tetrahydrofuran:2-ethoxy-ethanol (THF-2ETO) solvent system was found to have the best film quality. Adding 0.05 M 2ETO as the co-solvent is sufficient to produce high quality BiI3 and MBI thin films. According to the Xray photoelectron spectroscopy (XPS) analyzes, we have demonstrated that there is an interaction between BiI3 and 2ETO according to the concentration of 2ETO added to the main THF. Our study clarifies the importance of THF-2ETO solvent system that can accelerate the evolution of the Bi-based solar cells by creating high-quality BiI3 or MBI thin films.en_US
dc.description.sponsorshipPresidency of Turkish Republic Department of Strategy and Budget [2016K12-2841]; Scientific and Technical Research Council of Turkey (TUBITAK) [2211/C, 1649B031903340, 118Z948]en_US
dc.description.sponsorshipAuthors acknowledge to Presidency of Turkish Republic Department of Strategy and Budget for the financial support Project Grant Nr: 2016K12-2841 and Scientific and Technical Research Council of Turkey (TUBITAK) for financial support of A. MUTLU within the Program Nr.: 2211/C (Grant Nr.:1649B031903340) and for financial support of T. YESIL (Grant Nr.: 118Z948) .en_US
dc.identifier.doi10.1016/j.orgel.2021.106191
dc.identifier.issn1566-1199
dc.identifier.issn1878-5530
dc.identifier.issn1566-1199en_US
dc.identifier.issn1878-5530en_US
dc.identifier.scopus2-s2.0-85106571460en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.urihttps://doi.org/10.1016/j.orgel.2021.106191
dc.identifier.urihttps://hdl.handle.net/11454/76794
dc.identifier.volume95en_US
dc.identifier.wosWOS:000659914500003en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofOrganic Electronicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMethyl ammonium bismuth iodideen_US
dc.subjectLead-freeen_US
dc.subjectGreen solventsen_US
dc.subjectSolar cellsen_US
dc.subjectPerovskite Solar-Cellsen_US
dc.subjectLead-Freeen_US
dc.subjectCrystallizationen_US
dc.subjectMorphologyen_US
dc.subjectPerformanceen_US
dc.subjectDepositionen_US
dc.subjectEfficiencyen_US
dc.subjectEvolutionen_US
dc.subjectThicknessen_US
dc.subjectAbsorberen_US
dc.titleUtilization of coordinating green solvents for high quality methylammonium bismuth iodide thin films for photovoltaic applicationsen_US
dc.typeArticleen_US

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