1,3-Bis(thio-phen-2-ylmeth-yl)-3,4,5,6-tetrahydropyrimidinium trichlorido(µ6-pcymene)ruthenate(II)

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dc.contributor.authorArslan H.
dc.contributor.authorVanderveer D.
dc.contributor.authorÖzdemir S.
dc.contributor.authorGürbüz N.
dc.contributor.authorGök Y.
dc.contributor.authorÇetinkaya B.
dc.date.accessioned2019-10-27T08:36:26Z
dc.date.available2019-10-27T08:36:26Z
dc.date.issued2008
dc.departmentEge Üniversitesien_US
dc.description.abstractThe asymmetric unit of the title compound, (C14H17N2S2)[Ru(C10H14)Cl3], contains a 1,3-bis-(thio-phen-2-ylmeth-yl)-3,4,5,6-tetra-hydro-pyrimidinium cation and a trichlorido(µ6-p-cymene)ruthenate(II) anion. The Ru atom exhibits a distorted octa-hedral coordination with the benzene ring of the p-cymene ligand formally occupying three sites and three chloride atoms occupying the other three sites. The N - C bond lengths of the N - C - N unit of the pyrimidinium cation are shorter than the average single C - N bond length of 1.48 Å, thus showing double-bond character, indicating a partial electron delocalization within the N - C - N fragment. The pyrimidine ring has an envelope conformation. Four inter-molecular C - H?Cl hydrogen bonds generate a three-dimensional hydrogen-bonded framework.en_US
dc.identifier.doi10.1107/S1600536808042773
dc.identifier.endpagem112en_US
dc.identifier.issn1600-5368
dc.identifier.issn1600-5368en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpagem111en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536808042773
dc.identifier.urihttps://hdl.handle.net/11454/27389
dc.identifier.volume65en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofActa Crystallographica Section E: Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.title1,3-Bis(thio-phen-2-ylmeth-yl)-3,4,5,6-tetrahydropyrimidinium trichlorido(µ6-pcymene)ruthenate(II)en_US
dc.typeArticleen_US

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