Access to 3-Methyl-4-methylene-N-tosylpyrrolidine and 3,4-Dimethyl-N-tosylpyrroline by Ruthenium-Catalyzed Cascade Cycloisomerization/Isomerization Reactions
Küçük Resim Yok
Tarih
2004
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley-VCH Verlag
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
New RuCl2(benzimidazole)(arene) complexes have been prepared. Upon reaction with 1,1-diphenylprop-2-ynol they generate catalyst precursors which perform the cycloisomerization of diallyltosylamide into 3-methyl-4-methylene-N-tosylpyrrolidine. The presence of N-(2,4,6-trimethylbenzyl)benzimidazole as ligand leads to a subsequent isomerization and gives the 3,4-dimethyl-N-tosylpyrroline. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
Açıklama
Anahtar Kelimeler
Benzimidazole, Homogeneous catalysis, Olefination, Ruthenium
Kaynak
European Journal of Inorganic Chemistry
WoS Q Değeri
Scopus Q Değeri
Q2
Cilt
Sayı
2
