Thermokinetic analysis and product characterization of waste tire-hazelnut shell co-pyrolysis: TG-FTIR and fixed bed reactor study

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dc.authorscopusid57192697732
dc.authorscopusid7003728792
dc.authorwosidSÖYLER, NEJMİ/GZG-5638-2022
dc.contributor.authorSoyler, Nejmi
dc.contributor.authorCeylan, Selim
dc.date.accessioned2023-01-12T19:55:16Z
dc.date.available2023-01-12T19:55:16Z
dc.date.issued2021
dc.departmentN/A/Departmenten_US
dc.description.abstractThe synergetic effects during co-pyrolysis of waste tires and hazelnut shell biomass were investigated concerning the product distribution and reaction kinetics. The components were blended at different ratios and investigated using a thermogravimetric analyzer coupled with a Fourier Transform Infrared spectrometer. Kinetic parameters were calculated for the blends by Distributed Activation Energy Model, Straink, and Ozawa-Flynn-Wall; activation energies varied between 100 and 300 kJ mol(-1). Theoretical mass loss and activation energy results showed a synergetic interaction between components, especially for the 80% waste tire and 20% hazelnut shell biomass blends. Pyrolytic oil obtained from fixed bed experiments was analyzed by GC/MS, H-1 NMR, and FTIR. Although the contents were similar, significant variations in intensities were observed. Elemental analysis showed the deoxygenation effect of co-pyrolysis with lower oxygen content and higher heating value for pyrolytic oil. The results showed that co-pyrolysis of these types of waste has the potential to be co-processed for liquid fuel production with improved properties.en_US
dc.identifier.doi10.1016/j.jece.2021.106165
dc.identifier.issn2213-2929
dc.identifier.issn2213-3437
dc.identifier.issn2213-2929en_US
dc.identifier.issn2213-3437en_US
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-85112128749en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.jece.2021.106165
dc.identifier.urihttps://hdl.handle.net/11454/76648
dc.identifier.volume9en_US
dc.identifier.wosWOS:000703611000001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Sci Ltden_US
dc.relation.ispartofJournal Of Environmental Chemical Engineeringen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectWaste tireen_US
dc.subjectHazelnut shellen_US
dc.subjectCo-pyrolysisen_US
dc.subjectTG-FTIRen_US
dc.subjectKineticsen_US
dc.subjectFixed-bed reactoren_US
dc.subjectPy-Gc/Msen_US
dc.subjectBiomassen_US
dc.subjectOilen_US
dc.subjectEnhancementen_US
dc.subjectCombustionen_US
dc.subjectKineticsen_US
dc.subjectStrawen_US
dc.titleThermokinetic analysis and product characterization of waste tire-hazelnut shell co-pyrolysis: TG-FTIR and fixed bed reactor studyen_US
dc.typeArticleen_US

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