Novel rhodium N-heterocyclic carbene catalysed arylation of aldehydes with phenylboronic acid
| dc.contributor.author | Yigit, Murat | |
| dc.contributor.author | Ozdemir, Ismail | |
| dc.contributor.author | Cetinkaya, Engin | |
| dc.contributor.author | Cetinkaya, Bekir | |
| dc.date.accessioned | 2019-10-27T19:34:58Z | |
| dc.date.available | 2019-10-27T19:34:58Z | |
| dc.date.issued | 2007 | |
| dc.department | Ege Üniversitesi | en_US |
| dc.description.abstract | Reaction of 1,3-dialkylperhydrobenzimidazolinylidene, 1,3-dialkyl-4-methylimidazolinylidene and 1,3-dialkylimidazolinylidene with [RhCl(COD)](2) yields {1,3-dialkylperhydrobenzimidazolin- 2-ylidene}-, {1,3-dialkyl-4-methylimidazolin- 2-ylidene}- {1,3-dialkylimidazolin-2-ylidene} chloro(eta(4)- 1,5- cyclooctadiene) rhodium(I) complexes (2a-c) and ( 4a, b). All compounds synthesised were characterised by elemental analysis, n.m.r. spectroscopy. Phenylboronic acid reacts with aldehydes in the presence of a catalytic amount of the new rhodium(I)-carbene complexes (2a-c) and (4a, b), to give the corresponding aryl secondary alcohols in good yield (73-99%). | en_US |
| dc.identifier.doi | 10.1007/s11243-007-0208-4 | |
| dc.identifier.endpage | 540 | en_US |
| dc.identifier.issn | 0340-4285 | |
| dc.identifier.issn | 0340-4285 | en_US |
| dc.identifier.issue | 4 | en_US |
| dc.identifier.scopusquality | Q2 | en_US |
| dc.identifier.startpage | 536 | en_US |
| dc.identifier.uri | https://doi.org/10.1007/s11243-007-0208-4 | |
| dc.identifier.uri | https://hdl.handle.net/11454/39677 | |
| dc.identifier.volume | 32 | en_US |
| dc.identifier.wos | WOS:000246637100021 | en_US |
| dc.identifier.wosquality | Q3 | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.indekslendigikaynak | Scopus | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Springer | en_US |
| dc.relation.ispartof | Transition Metal Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | Novel rhodium N-heterocyclic carbene catalysed arylation of aldehydes with phenylboronic acid | en_US |
| dc.type | Article | en_US |
