Synthesis and characterization of metal carbonyl complexes of M(CO)(6)(M = Cr, Mo, and W), Re(CO)(5)Br, and Mn(CO)(3)CP with - Acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)

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dc.contributor.authorOzdemir, U
dc.contributor.authorKaracan, N
dc.contributor.authorSenturk, OS
dc.contributor.authorSert, S
dc.contributor.authorUgur, F
dc.date.accessioned2019-10-27T19:03:40Z
dc.date.available2019-10-27T19:03:40Z
dc.date.issued2004
dc.departmentEge Üniversitesien_US
dc.description.abstractTen new complexes, [M(CO)(5)(amsh)] [M = Cr; (1a), Mo; (2a), W; (3a)], [Re(CO)(4)Br(amsh)] (4a), and [Mn(CO)(2)(amsh)Cp] (5a) and [M(CO)(5) (msh)] [M = Cr; (1b); Mo, (2b); W, (3b)], [Re(CO)4Br(msh)], (4b), and [Mn(CO)(3)(msh)], (5b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO)(6)] (M = Cr, Mo, and W), [Re(CO)(5)Br], and [Mn(CO)(3)Cp] with acetonemethanesulfonylhydrazone (amsh) and methanesulfonyl hydrazine (msh). The complexes have been characterized by elemental analyses, mass spectrometry, FT-IR and H-1 NMR spectroscopy. The spectroscopic studies show that amsh and msh behave as a monodentate ligands coordinating via an imine N donor atom in (1a)-(5a) and a hydrazine N donor atom in (1b)-(5b).en_US
dc.identifier.doi10.1081/SIM-120037527
dc.identifier.endpage1067en_US
dc.identifier.issn0094-5714
dc.identifier.issn0094-5714en_US
dc.identifier.issue6en_US
dc.identifier.startpage1057en_US
dc.identifier.urihttps://doi.org/10.1081/SIM-120037527
dc.identifier.urihttps://hdl.handle.net/11454/38138
dc.identifier.volume34en_US
dc.identifier.wosWOS:000222582700006en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic and Metal-Organic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectmetal carbonyl complexesen_US
dc.subjectmethanesulfonylhydrazoneen_US
dc.subjectmonodentate ligandsen_US
dc.subjectSchiff baseen_US
dc.titleSynthesis and characterization of metal carbonyl complexes of M(CO)(6)(M = Cr, Mo, and W), Re(CO)(5)Br, and Mn(CO)(3)CP with - Acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)en_US
dc.typeArticleen_US

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