New (kappa(2)-C,N)-palladacyclic complexes with benzimidazol-2-ylidene ligand: Synthesis, crystal structures and characterization

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dc.contributor.authorGunay, M. Emin
dc.contributor.authorGumuesada, Rukiye
dc.contributor.authorOzdemir, Namik
dc.contributor.authorDincer, Muharrem
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2019-10-27T20:49:01Z
dc.date.available2019-10-27T20:49:01Z
dc.date.issued2009
dc.departmentEge Üniversitesien_US
dc.description.abstractReaction of unsymmetrical benzimidazolium bromides (1) with Ag2O and subsequent transmetallation with chloro-bridged dinuclear palladacycle, [Pd(dmba)(mu-Cl](2) (dmba: N,N-dimethylbenzylamine) afforded benzannulated monocarbene complexes [Pd(dmba)(NHC)Cl], 2. The palladacycles (2a-c) were characterized by elemental analysis; NMR spectroscopy and the molecular structure of 2a and 2c were determined by X-ray crystallography. (C) 2009 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [104T 203]; Adnan Menderes UniversityAdnan Menderes University [FEF-07006, FEF-07013, FBE-08001]; Ondokuz Mayis UniversityOndokuz Mayis University [F-461]en_US
dc.description.sponsorshipFunding of our research from the TUBITAK (Project No.: 104T 203). Adnan Menderes University (Project Nos.: FEF-07006, FEF-07013 and FBE-08001) and Ondokuz Mayis University (Project No.: F-461) is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.inoche.2009.08.001
dc.identifier.endpage993en_US
dc.identifier.issn1387-7003
dc.identifier.issn1387-7003en_US
dc.identifier.issue10en_US
dc.identifier.startpage990en_US
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2009.08.001
dc.identifier.urihttps://hdl.handle.net/11454/42800
dc.identifier.volume12en_US
dc.identifier.wosWOS:000271356300015en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofInorganic Chemistry Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPalladacyclesen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectUnsymmetrical benzimidazolium salten_US
dc.subjectCrystal structureen_US
dc.titleNew (kappa(2)-C,N)-palladacyclic complexes with benzimidazol-2-ylidene ligand: Synthesis, crystal structures and characterizationen_US
dc.typeArticleen_US

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