Synthesis, characterization, and reactivity of ruthenium(II) complexes containing ? 6-arene-? 1-pyrazole ligands
Küçük Resim Yok
Tarih
2012
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
New ruthenium(II) complexes containing ? 6-arene- ? 1-pyrazole ligands were synthesized and characterized by elemental analysis and spectroscopic methods. In addition, the molecular structure of dichloro-3,5-dimethyl-1-(pentamethylbenzyl)-pyrazole-ruthenium(II), [Ru]L 3b, was determined by X-ray diffraction studies. These complexes were applied in the transfer hydrogenation of acetophenone by isopropanol in the presence of potassium hydroxide. The activities of the catalysts were monitored by NMR. © 2012 Elsevier Ltd.
Açıklama
Anahtar Kelimeler
Arene-ruthenium(II) complexes, Half-sandwich complexes, Pyrazole, Transfer hydrogenation
Kaynak
Tetrahedron
WoS Q Değeri
Scopus Q Değeri
Q2
Cilt
68
Sayı
41
