Photochemical reactions of Re(CO)(5)Br with tetraalkyldiphosphine disulfides (R=Me, Et, Pr-n, Bu-n, Ph) and the crystal structure of [ReBr(CO)(3)(Et2P(S)P(S)Et-2)]
| dc.contributor.author | Senturk, OS | |
| dc.contributor.author | Shekhel, HA | |
| dc.contributor.author | Sterenberg, BT | |
| dc.contributor.author | Udachin, KA | |
| dc.contributor.author | Sert, S | |
| dc.contributor.author | Ozdemir, U | |
| dc.contributor.author | Sarikahya, FU | |
| dc.date.accessioned | 2019-10-27T18:39:13Z | |
| dc.date.available | 2019-10-27T18:39:13Z | |
| dc.date.issued | 2003 | |
| dc.department | Ege Üniversitesi | en_US |
| dc.description.abstract | The hitherto unknown series of complexes fac-[Re(CO)(3)Br{R2P(S)P(S)R-2}] 1a-5a (1a, R = Me; 2a, R = Et; 3a, R = Pr-n; 4a, R = Bu-n; 5a, R = Ph) and [Re-2(CO)(8)Br-2{cis-mu-R2P(S)P(S)R-2}] 1b-5b [1b, R = Me; 2b, R = Et; 3b, R = Pr-n; 4b, R = Bu-n; 5b, R = Ph] have been prepared by the photochemical reaction of Re(CO)(5)Br with R2P(S)P(S)R-2. The complexes have been characterized by elemental analysis, mass spectroscopy (EI), FT-IR and P-31{H-1} NMR spectrometry. The spectroscopic studies suggest cis-chelate bidentate coordination of the ligand in fac-[Re(CO)(3)Br{R2P(S)P(S)R-2}] and cis-bridging bidentate coordination of the ligand between two metals in [Re-2(CO)(8)Br-2{cis-mu-R2P(S)P(S)R-2}] (R = Me, Et, Pr-n, Bu-n, Ph). An X-ray diffraction study of [ReBr(CO)(3)(Et2P(S)P(S)Et-2)] confirms that the rhenium, adopts a distorted octahedral geometry with local C-5 symmetry. (C) 2003 Elsevier Science Ltd. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/S0277-5387(03)00327-9 | |
| dc.identifier.endpage | 1664 | en_US |
| dc.identifier.issn | 0277-5387 | |
| dc.identifier.issue | 13 | en_US |
| dc.identifier.startpage | 1659 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/S0277-5387(03)00327-9 | |
| dc.identifier.uri | https://hdl.handle.net/11454/36734 | |
| dc.identifier.volume | 22 | en_US |
| dc.identifier.wos | WOS:000184113200005 | en_US |
| dc.identifier.wosquality | Q2 | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
| dc.relation.ispartof | Polyhedron | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | diphosphine disulfide | en_US |
| dc.title | Photochemical reactions of Re(CO)(5)Br with tetraalkyldiphosphine disulfides (R=Me, Et, Pr-n, Bu-n, Ph) and the crystal structure of [ReBr(CO)(3)(Et2P(S)P(S)Et-2)] | en_US |
| dc.type | Article | en_US |
