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Öğe Electrochemical Behavior of Disposable Electrodes Prepared by Ion Beam Based Surface Modification for Biomolecular Recognition(Amer Inst Physics, 2009) Erdem, A.; Urkac, E. Sokullu; Karadeniz, H.; Caliskan, A.; Oks, E.; Nikolayev, A.; Oztarhan, A.; McDaniel, FD; Doyle, BLMany important technological advances have been made in the development of technologies to monitor interactions and recognition events of biomolecules in solution and on solid substrates. The development of advanced biosensors could impact significantly the areas of genomics, proteomics, biomedical diagnostics and drug discovery. In the literature, there have recently appeared an impressive number of intensive designs for electrochemical monitoring of biomolecular recognition. Herein, the influence of ion implanted disposable graphite electrodes on biomolecular recognition and their electrochemical behaviour was investigated.Öğe Nanoscale surface modification of UltraHigh Molecular Weight Polyethylene (UHMWPE) samples with the W plus C ion implantation(Materials Research Soc, 2007) Urkac, E. Sokullu; Oztarhan, A.; Tihminlioglu, F.; Kaya, N.; Budak, S.; Chhay, B.; Muntele, C.; Oks, E.; Nikolaev, A.; Ila, D.; Ila, D; Baglin, J; Kishimoto, N; Chu, PKIn this work, Ultra High Molecular Weight Poly Ethylene (UHMWPE) samples Were implanted by W + C ions using Metal-Vapour Vacuum Arc (MEVVA) ion implantation system with a fluence of 10(17) ion/cm(2) and extraction voltage of 30 kV. Samples were characterized with Raman Spectra, ATR-FTIR, UV-VIS-NlR Spectrum and RBS. Surface morphology of implanted and unimplanted samples were examined in nanoscale with AFM.Öğe Structural and Thermal Characterization of Ti plus O Ion Implanted UltraHigh Molecular Weight Polyethylene (UHMWPE)(Amer Inst Physics, 2009) Oztarhan, A.; Urkac, E. Sokullu; Tihminlioglu, F.; Kaya, N.; Ila, D.; Budak, S.; Chhay, B.; Muntele, C.; Oks, E.; Nikolaev, A.; McDaniel, FD; Doyle, BLIn this work, Metal-Gas Hybrid Ion Implantation technique was used as a tool for the surface modification of Ultra High Molecular Weight Polyethylene (UHMWPE). Samples were Ti + O ion implanted by using Metal-Vapour Vacuum Arc (MEVVA) ion implanter to a fluence of 5x10(16) ion/cm(2) for each species and extraction voltage of 30 kV. Untreated and surface treated samples were investigated by Rutherford Back Scattering (RBS) Spectrometry, Attenuated Total Reflectance - Fourier Transform Infrared (ATR-FTIR) Spectroscopy, Thermo Gravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). Results indicate that Ti + O ion implantation can be applied on UHMWPE surfaces successfully. ATR-FTIR spectra indicate that the C-H concentration on the surface decreased after Ti + O implantation. Thermal characterization with TGA and DSC shows that polymeric decomposition temperature is shifted after ion implantation.Öğe Thermal Behaviour of W plus C Ion Implanted Ultra High Molecular Weight Polyethylene (UHMWPE)(Amer Inst Physics, 2009) Urkac, E. Sokullu; Oztarhan, A.; Tihminlioglu, F.; Ila, D.; Budak, S.; Chhay, B.; Muntele, C.; Oks, E.; Nikolaev, A.; McDaniel, FD; Doyle, BLThe aim of this work was to examine thermal behavior of the surface modified Ultra High Molecular Weight Poly Ethylene (UHMWPE) in order to understand the effect of ion implantation on the properties of this polymer which is widely used especially for biomedical applications. UHMWPE samples were Tungsten and Carbon (W+C) hybrid ion implanted by using Metal Vapour Vacuum Arc (MEVVA) ion implantation technique with a fluence of 10 17 ions/cm2 and extraction voltage of 30kV. Untreated and surface-treated samples were investigated by Rutherford Back Scattering (RBS) Analysis, Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) Spectrometry, Thermo Gravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). This study has shown that ion implantation represents a powerful tool on modifying thermal properties of UHMWPE surfaces. This combination of properties can make implanted UHMWPE a preferred material for biomedical applications.Öğe Thermal characterization of Ag and Ag plus N ion implanted ultra-high molecular weight polyethylene (UHMWPE)(Elsevier Science Bv, 2007) Urkac, E. Sokullu; Oztarhan, A.; Tihminlioglu, F.; Kaya, N.; Ila, D.; Muntele, C.; Budak, S.; Oks, E.; Nikolaev, A.; Ezdesir, A.; Tek, Z.Most of total hip joints are composed of ultra-high molecular weight polyethylene (UHMWPE). However, as ultra-high molecular weight polyethylene is too stable in a body, wear debris may accumulate and cause biological response such as bone absorption and loosening of prosthesis. In this study, ultra-high molecular weight polyethylene samples were Ag and Ag + N hybrid ion implanted by using MEVVA ion implantation technique to improve its surface properties. Samples were implanted with a fluence of 10(17) ion/cm(2) and extraction voltage of 30 kV. Implanted and unimplanted samples were investigated by thermo-gravimetry analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), optical microscopy (OM) and contact Angle measurement. Thermal characterization results showed that the ion bombardment induced an increase in the % crystallinity, onset and termination degradation temperatures of UHMWPE. (c) 2007 Elsevier B.V. All rights reserved.