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    Synthesis and beta particle excited thermoluminescence of BaSiF6 phosphor
    (Pergamon-Elsevier Science Ltd, 2022) Souadi, G.; Akca-Ozalp, S.; Karali, E. Ekdal; Kaynar, U. H.; Ayvacikli, M.; Topaksu, M.; Can, N.
    BaSiF6 phosphor was synthesized by a gel combustion method. The crystalline size was found to be 54.17 +/- 4.36 nm using Williamson-Hall (W-H) approximation. The TL data collected by means of a combination of a commercial BG39 and HC575/25 filters was studied to evaluate basic kinetic parameters. Three TL glow peaks of BaSiF6 phosphors are centered at around 84, 190 and 322 degrees C. T-m-T-stop, various heating rate (VHR) and computerized glow-curve deconvolution (CGCD) method were utilized to analyse collected data. Our findings indicate that luminescence process in scrutinized material may obey second order kinetics. The TL dose response of the TL glow peaks exhibits a linear characteristic up to 100 Gy. Deconvolution of the glow curve reveals that the number of the component TL glow peaks in the complex glow curve is composed of well-isolated six overlapping glow peaks. The FOM value is 2.32.
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    Thermal quenching and evaluation of trapping parameters of thermoluminescence glow-peaks of beta irradiated NaBaBO3: Tb3+ for TLD applications
    (Elsevier, 2022) Oglakci, M.; Topaksu, M.; Alajlani, Y.; Can, N.; Karali, E. Ekdal
    Here, we report the thermoluminescence (TL) characteristics and trapping parameters under beta ray excitations of pelletized Tb incorporated NaBaBO3 synthesized through the gel combustion method. The chemical composition of this new phosphor was confirmed using X-ray diffraction (XRD). The best doping concentration of Tb was 2 mass%, which results in the highest luminous efficiency. The glow curves of the pellet-formed samples exposed to beta irradiation at various doses showed glow peaks at about 188 degrees C, and 288 degrees C with a heating rate of 2 degrees Cs-1. The trapping parameters (E, b, s) related with the prominent the TL glow peaks were determined using T-m-T-stop, initial rise (IR), computerized glow curve deconvolution (CGCD), and variable heating rate (VHR) methods. In the range of 0.1-40 Gy, the total integral values of TL output enlarge linearly with increased dose. The GCD approach was also used to calculate the number of the glow peaks necessary to ensure an appropriate match to the TL response of the phosphor sample and seven TL glow peaks were estimated for all doses (FOM 1.75%), similar to the analysis of T-m-T-stop. The thermal quenching parameters of Tb activated NaBaBO3 for the 1st and 2nd peaks are measured to be W = 0.39 +/- 0.04 eV, C = 3.11 x 10(2), and W = 0.31 +/- 0.03 eV, C = 3.11 x 10(2), respectively. The current results indicate that the NaBaBO3:Tb3+ phosphor is a suitable option in radiation dosimetry for environmental monitoring.