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    ARSENIC SORPTION USING MIXTURES OF ION EXCHANGE RESINS CONTAINING N-METHYL-D-GLUCAMINE AND QUATERNARY AMMONIUM GROUPS
    (Soc Chilena Quimica, 2016) Ozkula, Gulsah; Urbano, Bruno F.; Rivas, Bernabe L.; Kabay, Nalan; Bryjak, Marek
    The method of synthesis and the arsenic removal properties of ion-exchange resins based on N-methyl-D-glucamine and trimethylammonium groups are presented. The N-methyl-D-glucamine based monomer was synthesized by the reaction of 4-vinyl benzyl chloride with N-methyl-D-glucamine, along with the use of N, N-methylene-bis-acrylamide as a crosslinker reagent for polymerization. In addition, poly(4-vinylbenzyl) trimethylammonium was synthesized. Arsenate sorption studies were conducted and the pH effect, kinetics, sorption capacity, and elution performance were studied. The experimental data were fitted to kinetic models, such as the pseudo-first order and pseudo-second order models. The pseudo-second order model exhibited the best correlation with the experimental data. The Langmuir and Freundlich isotherms were fitted to the experimental data, and the Freundlich isotherm exhibited the best fit.
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    Removal of boron from geothermal water by a novel boron selective resin
    (Elsevier, 2013) Santander, Paola; Rivas, Bernabe L.; Urbano, Bruno F.; Ipek, Idil Yilmaz; Ozkula, Gulsah; Arda, Muserref; Yuksel, Mithat; Bryjak, Marek; Kozlecki, Tomasz; Kabay, Nalan
    In this study, a novel chelating resin poly(N-(4-vinylbenzyl)-N-methyl-o-glucamine) (P(VbNMDG)) was synthesized. The sorption performance of this resin was compared with boron selective commercial resin Diaion CRB02 containing N-methyl-n-glucamine (NMDG) groups for boron removal from geothermal water. The P(VbNMDG) resin gave a higher sorption capacity and faster kinetics than that of Diaion CRB02 for boron removal from geothermal water. The kinetic data obtained were evaluated using classical kinetic models and diffusion/reaction models. It was concluded that both P(VbNMDG) and Diaion CRB02 resins obeyed pseudo second order kinetic model. Also, the rate controlling step of boron sorption was particle diffusion for both resins. The breakthrough profile of P(VbNMDG) resin for boron was sharper than that of Diaion CRB02. Thus, the degree of the column utilization of P(VbNMDG) resin was also high. The boron loaded on both resins was eluted using 5% H2SO4 solution with a percentage of around 80%. (C) 2012 Elsevier B.V. All rights reserved.
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    Removal of boron from geothermal water by a novel boron selective resin
    (Elsevier, 2013) Santander, Paola; Rivas, Bernabe L.; Urbano, Bruno F.; Ipek, Idil Yilmaz; Ozkula, Gulsah; Arda, Muserref; Yuksel, Mithat; Bryjak, Marek; Kozlecki, Tomasz; Kabay, Nalan
    In this study, a novel chelating resin poly(N-(4-vinylbenzyl)-N-methyl-o-glucamine) (P(VbNMDG)) was synthesized. The sorption performance of this resin was compared with boron selective commercial resin Diaion CRB02 containing N-methyl-n-glucamine (NMDG) groups for boron removal from geothermal water. The P(VbNMDG) resin gave a higher sorption capacity and faster kinetics than that of Diaion CRB02 for boron removal from geothermal water. The kinetic data obtained were evaluated using classical kinetic models and diffusion/reaction models. It was concluded that both P(VbNMDG) and Diaion CRB02 resins obeyed pseudo second order kinetic model. Also, the rate controlling step of boron sorption was particle diffusion for both resins. The breakthrough profile of P(VbNMDG) resin for boron was sharper than that of Diaion CRB02. Thus, the degree of the column utilization of P(VbNMDG) resin was also high. The boron loaded on both resins was eluted using 5% H2SO4 solution with a percentage of around 80%. (C) 2012 Elsevier B.V. All rights reserved.