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    Demineralization of cheese whey by sequential nanofiltration (NF) and electrodialysis (ED) processes
    (Amirkabir University of Technology - Membrane Processes Research Laboratory, 2019) Kaya, N.; Altiok, E.; Gökkaya, D.S.; Kabay, N.; Ötleş, S.
    In this study, demineralization of cheese whey by sequential nanofiltration (NF) and electrodialysis (ED) methods was investigated. For the NF step, two NF membranes labeled as NF-270 and NF-90 were tested. Approximately 90% of protein and lactose rejections were obtained with partial demineralization during NF step. For full demineralization of the NF permeate, NF followed by ED process. Two different ED systems (Tokuyama TS-1-10 with Neosepta membranes and Mega EDZ-10x4-0.8 with Ralex membranes) were used. The rejections of Na+, K+, Ca2+, and Mg2+ ions from the NF permeate with Ralex membranes were calculated as 82.5%, 99.3%, 87.9%, and 92.9%, while the corresponding values were 80.2%, 99.0%, 95.6%, and 100% by Neosepta membranes, respectively. © 2019 MPRL. All rights reserved.
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    Salinity gradient energy conversion by custom-made interpolymer ion exchange membranes utilized in reverse electrodialysis system
    (Elsevier Ltd, 2023) Altiok, E.; Kaya, T.Z.; Smolinska-Kempisty, K.; Güler, E.; Kabay, N.; Tomaszewska, B.; Bryjak, M.
    Reverse electrodialysis (RED) is one of methods to extract salinity gradient energy between two aqueous solutions with different salt concentrations. In this work, custom-made interpolymer ion exchange membranes were employed in the RED stack. The effects of divalent (Mg2+, Ca2+ and SO42-) and monovalent (Li+, K+ and Cl-) ions in the feed solutions prepared from NaCl salt as a function of such process parameters as number of membrane pairs, flow rate, and salinity ratio on power generation by the RED method were studied. It was shown that the maximum power density of 0.561 W/m2 was reached by using three membrane pairs using 1:45 of salt ratio with a feed flow rate of 120 mL/min using only NaCl salt in the feed solutions. The maximum power density was 0.398 W/m2 at 120 mL/min of the flow rate of the feed solutions composed of 90 wt% NaCl and 10 wt% KCl by using a salt ratio of 1:30 while the lowest power density of 0.246 W/m2 was obtained with a feed flow rate of 30 mL/min in the presence of SO42- ions with a similar salt ratio. Consequently, it was seen that while the presence of divalent ions in NaCl solutions had negative impact on power generation by RED system, the addition of monovalent ions having smaller hydrated radius than that of the Na+ ions contributed positively to the power generation. © 2023 Elsevier Ltd.