Senturk, OSOzdemir, USert, SKaracan, NUgur, F2019-10-272019-10-2720031387-70031387-7003https://doi.org/10.1016/S1387-7003(03)00152-7https://hdl.handle.net/11454/36721Five new complexes, [M(CO)(5)(apesh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)(4) Br(apesh)] (4) and [Mn(CO)(3)(apesh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)(6)] (M = Cr, Mo, W), [Re(CO)(5) Br], and [Mn(CO)3 Cp] with 2-hydroxyacetophenone ethanesulfonylhydrazone (apesh). The complexes have been characterized by elemental analysis, mass spectrometry, FT-IR, H-1 NMR spectroscopy. The spectroscopic studies show that apesh behaves as a monodentate ligand coordinating via imine N donor atom in (1)-(4) and as tridentate ligand in (5). (C) 2003 Elsevier Science B.V. All rights reserved.en10.1016/S1387-7003(03)00152-7info:eu-repo/semantics/closedAccessphotosubstituton2-hydroxyacetophenone ethanesulfonylhydrazonemetal carbonylsArticle67926929WOS:000183745800032N/AQ2