Gülcemal D.Masullo M.Alankuş-Çalişkan O.Karayildirim T.Şenol S.G.Piacente S.Bedir E.2019-10-262019-10-2620100749-1581https://doi.org/10.1002/mrc.2559https://hdl.handle.net/11454/19970A new secondary metabolite, pterocephaline, along with the known cantleyoside, 7´-morroniside, 3ß,5´-tetrahydrodesoxycordifoline lactam, 5S-5-carboxyvincoside, sweroside, and loganin have been isolated from the aerial parts of P. pinardii (Dipsacaceae). Moreover, cantleyoside-methyl- hemiacetal and cantleyoside-dimethyl-acetal were obtained as seco-iridoid artifacts. The structures were elucidated by extensive spectroscopic methods including 1D-(1H, 13C and TOCSY) and 2D-NMR(DQF-COSY, HSQC and HMBC). Monoterpenoid glucoindole alkaloids were encountered for the first time in Dipsacaceae family. Copyright © 2010 John Wiley & Sons, Ltd.en10.1002/mrc.2559info:eu-repo/semantics/closedAccessArtifactCantleyoside-methyl-hemiacetalDipsacaceaeIridoidMonoterpenoid glucoindole alkaloidNMRPterocephalinePterocephalusArticle48323924320049748Q2