Sahin, C.Dittrich, Th.Varlikli, C.Icli, S.Lux-Steiner, M. Ch.2019-10-272019-10-2720100927-02480927-0248https://doi.org/10.1016/j.solmat.2009.11.008https://hdl.handle.net/11454/43995Symposium on Mesoscopic Dye Sensitized and Organic Heterojunction Solar Cells held at the e-MRS 2009 Spring Meeting -- 2009 -- Strasbourg, FRANCEThe influence of molecular side groups on the electron backtransfer into ruthenium-dye molecules adsorbed on ultra-thin nanoporous TiO2 layers has been investigated by modulated surface photovoltage spectroscopy in argon atmosphere. All ruthenium-dye molecules contained one bipyridine (bpy) ligand with two carboxylic groups for anchoring at the TiO2 surface. Ruthenium (II) complexes with a second bpy ligand with branching and non-branching side groups containing C and H only and ruthenium (II) complexes with a second pyridine (py) ligand with side groups containing different numbers of -C-O-C- sequences were synthesized. The electron backtransfer was practically not affected by branching or non-branching side groups in the bpy-bpy complexes. In contrast, electron backtransfer was much less for bpy-py complexes in comparison to bpy-bpy complexes and increased strongly with increasing number of -C-O-C- sequences in the side groups. (C) 2009 Elsevier B.V. All rights reserved.en10.1016/j.solmat.2009.11.008info:eu-repo/semantics/closedAccessRuthenium (II) complexSurface photovoltage spectroscopyElectron backtransferTitanium dioxideArticle944686690WOS:000276718500010Q1