Gunay, M. EminGumuesada, RukiyeOzdemir, NamikDincer, MuharremCetinkaya, Bekir2019-10-272019-10-2720091387-70031387-7003https://doi.org/10.1016/j.inoche.2009.08.001https://hdl.handle.net/11454/42800Reaction of unsymmetrical benzimidazolium bromides (1) with Ag2O and subsequent transmetallation with chloro-bridged dinuclear palladacycle, [Pd(dmba)(mu-Cl](2) (dmba: N,N-dimethylbenzylamine) afforded benzannulated monocarbene complexes [Pd(dmba)(NHC)Cl], 2. The palladacycles (2a-c) were characterized by elemental analysis; NMR spectroscopy and the molecular structure of 2a and 2c were determined by X-ray crystallography. (C) 2009 Elsevier B.V. All rights reserved.en10.1016/j.inoche.2009.08.001info:eu-repo/semantics/closedAccessPalladacyclesN-heterocyclic carbeneUnsymmetrical benzimidazolium saltCrystal structureArticle1210990993WOS:000271356300015Q2