Highly soluble perylene dyes: Synthesis, photophysical and electrochemical characterizations

Küçük Resim Yok

Tarih

2009

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier Sci Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Highly soluble perylene diimide derivatives with symmetrical and unsymmetrical secondary, tertiary alkyl side chains were synthesized and their photophysical properties, redox potentials and thermal stabilities were measured and compared with previously reported 1-pentylhexyl substituted swallow-tailed perylene diimide. Diasteroisomers of the novel, unsymmetrical swallow-tailed substituted perylene diimide compound could not be detected using low temperature NMR spectroscopy. The novel dyes were soluble in a range of organic solvents indicating potential for photo-electronic applications and photocatalytic reactions. Two dyes were not only soluble in organic solvents but also showed solubility in aqueous media as the hydrochloride salt, thus offering potential use in biological applications. (C) 2009 Elsevier Ltd. All rights reserved.

Açıklama

Anahtar Kelimeler

Perylene dyes, Swallow-tailed substituted perylene diimides, Photophysical properties, Electrochemical characterization, Soluble dyes, Fluorescent dyes

Kaynak

Dyes and Pigments

WoS Q Değeri

Q1

Scopus Q Değeri

Q1

Cilt

83

Sayı

3

Künye