Synthesis, characterization and catalytic properties of an N-heterocyclic carbene palladium-based complex

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dc.contributor.authorOzdemir, Ismail
dc.contributor.authorArslan, Hakan
dc.contributor.authorDemir, Serpil
dc.contributor.authorVanDerveer, Don
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2019-10-27T20:22:35Z
dc.date.available2019-10-27T20:22:35Z
dc.date.issued2008
dc.departmentEge Üniversitesien_US
dc.description.abstractA palladium(II) complex, bis[1,3-bis-(2,4,6-trimethylbenzyl)benzimidazol-2 -ylidene]palladium(II) chloride, Pd(NHC), bearing N-heterocyclic carbenes has been synthesized and characterized by elemental analysis, IR spectroscopy and H-1 and C-13 NMR spectroscopy. Crystal structure details of Pd(NHC) are also presented. The palladium centre in the complex lies on a crystallographic inversion centre and occupies a square-planar environment. with both chloride and N-heterocyclic carbene ligands adopting a trans arrangement with Cl-Pd-Cl and C-Pd-C angles are precisely 180 degrees. The palladium-carbene complex was tested as a catalyst in the Suzuki-Miyaura cross-coupling reaction. (c) 2008 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBiTAK-CNRSTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-U/181 (106T716)]en_US
dc.description.sponsorshipWe thank the Technological and Scientific Research Council of Turkey TUBiTAK-CNRS [TBAG-U/181 (106T716)] for financial support.en_US
dc.identifier.doi10.1016/j.inoche.2008.10.004
dc.identifier.endpage1465en_US
dc.identifier.issn1387-7003
dc.identifier.issn1879-0259
dc.identifier.issn1387-7003en_US
dc.identifier.issn1879-0259en_US
dc.identifier.issue12en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage1462en_US
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2008.10.004
dc.identifier.urihttps://hdl.handle.net/11454/41919
dc.identifier.volume11en_US
dc.identifier.wosWOS:000261859300013en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofInorganic Chemistry Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbenesen_US
dc.subjectPalladium-carbene complexesen_US
dc.subjectCrystal structureen_US
dc.subjectSuzuki-Miyaura cross-coupling reactionen_US
dc.subjectPalladium catalysten_US
dc.titleSynthesis, characterization and catalytic properties of an N-heterocyclic carbene palladium-based complexen_US
dc.typeArticleen_US

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