Alkyne insertion and coupling reactions mediated by the cycloheptatrienyl-bridged heterobimetallic complexes (mu-C7H7) Ru(CO)(3)M'(CO)(2) (M' = Rh, Ir)
Küçük Resim Yok
Tarih
2014
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Cycloheptatrienyl-bridged RuRh and RuIr pentacarbonyl complexes were found to undergo metal-carbon and carbon-carbon bond-forming reactions with hexafluoro-2-butyne to afford products in which coupling of the alkyne and cycloheptatrienyl group had occurred. Reaction of the RuRh complex occurred readily at room temperature whereas the RuIr complex required thermal activation of 100 degrees C, which resulted in incorporation of two alkyne units into the product. (C) 2014 Elsevier B. V. All rights reserved.
Açıklama
Anahtar Kelimeler
Heterobimetallic, Cycloheptatrienyl, Alkyne coupling, Hexafluoro-2-butyne
Kaynak
Journal of Organometallic Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Cilt
754
