Silver, palladium and rhodium complexes of acenaphthylene-anuilated N-heterocyclic carbene ligands: A comparative study

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dc.contributor.authorTurkmen, Hayati
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2019-10-27T19:39:47Z
dc.date.available2019-10-27T19:39:47Z
dc.date.issued2006
dc.departmentEge Üniversitesien_US
dc.description.abstractThe newly prepared carbene precursor 1,3-dimesitylacenaphtho[1,2-d]imidazolinium chloride, (NHC-H)Cl, 3, could be readily converted into the NHC-silver(l) complex, 4, which is an efficient carbene transfer agent and has been used to synthesise thione 5, trans-[PdCl2(NHC)(2)], 6 and [RhCl(NHC)(COD)], 7. All compounds synthesised were characterised by elemental analysis, NMR spectroscopy and the molecular structures of the thione 5 and complex 7 were determined by X-ray crystallography. Complex 7 was converted into cis-[RhCl(NHC)(CO)(2)] and the electron donating properties and trans influence of the NHC ligand were compared with nonamillated counterparts. The catalytic activity in the Heck reaction of 6 and the in situ formed palladium complex was evaluated. The activity of the in situ formed complexes for the Heck coupling of alkenes was high. (c) Wiley-VCH Verlag GmbH & Co.en_US
dc.identifier.doi10.1002/ejic.200600545
dc.identifier.endpage4921en_US
dc.identifier.issn1434-1948
dc.identifier.issn1099-0682
dc.identifier.issn1434-1948en_US
dc.identifier.issn1099-0682en_US
dc.identifier.issue23en_US
dc.identifier.startpage4915en_US
dc.identifier.urihttps://doi.org/10.1002/ejic.200600545
dc.identifier.urihttps://hdl.handle.net/11454/40202
dc.identifier.wosWOS:000243077400026en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbenesen_US
dc.subjectsilver complexesen_US
dc.subjectthionesen_US
dc.subjectpalladium complexesen_US
dc.subjectrhodium complexesen_US
dc.subjectC-C couplingen_US
dc.titleSilver, palladium and rhodium complexes of acenaphthylene-anuilated N-heterocyclic carbene ligands: A comparative studyen_US
dc.typeArticleen_US

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