Iridium(I)-Catalyzed Alkylation Reactions to Form ?-Alkylated Ketones
Küçük Resim Yok
Tarih
2018
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
American Chemical Society
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A highly effective and green procedure for the formation of ?-alkylated ketones has been disclosed via the reaction of primary alcohols with secondary alcohols and ketones by using [IrCl(COD)(NHC)] complexes as a catalyst. Various ?-alkylated ketones were obtained in high yields from the alkylation of alcohol with alcohol and ketone with alcohol through a borrowing hydrogen reaction by using 0.05-0.5 mol % iridium(I) and a catalytic amount of KOH (5-10 mol %) as the base under air atmosphere and within very short reaction times. © 2018 American Chemical Society.
Açıklama
Anahtar Kelimeler
Kaynak
Journal of Organic Chemistry
WoS Q Değeri
Scopus Q Değeri
N/A
Cilt
83
Sayı
5
