Synthesis, X-ray structural and thermal analysis of a novel copper compound containing dissymmetric independent 5- And 6-coordinate CuL(H<inf>2</inf>O)<inf>n</inf> (n = 2, 3) units and hydrogen bond bridges
Küçük Resim Yok
Tarih
2015
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Slovensko Kemijsko Drustvo
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The synthesis, thermogravimetric and X-ray structure analysis of a highly unusual copper compound prepared from a chiral tridentate Schiff base ligand is reported. The title compound [CuL(H<inf>2</inf>O)<inf>2</inf>] • [CuL(H<inf>2</inf>O)<inf>3</inf>] • H<inf>2</inf>O crystallizes in the orthorhombic crystal system in space group P2<inf>1</inf>2<inf>1</inf>2<inf>1</inf> with Z = 4. The two independent CuL(H<inf>2</inf>O)<inf>n</inf> complexes are present in the same unit cell, along with an uncoordinated water molecule. The five-coordinated copper(II) centre occupies a distorted square-pyramidal geometry whereas the six-coordinated copper(II) centre has a distorted octahedral geometry. The independent copper complexes and the uncoordinated water molecule are joined together with intermolecular hydrogen bonds in a two-dimensional supramolecular network which lies parallel to the ab plane.
Açıklama
Anahtar Kelimeler
2D supramolecular structure, Crystal structure, Schiff base cu(Ii) complex, Thermal analysis
Kaynak
Acta Chimica Slovenica
WoS Q Değeri
Scopus Q Değeri
Q3
Cilt
62
Sayı
1
