Investigation of photochemical reactions of some metal carbonyls with N´-(2-Hydroxy-6-methylbenzylidene)Methanesulfonohydrazide and 5-Methyl-2-hydroxyacetophenonemethanesulfonylhydrazone
Küçük Resim Yok
Tarih
2021
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Slovensko Kemijsko Drustvo
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Eight new complexes, [M(CO)5(5msalmsh)] [M=Cr;(1a), Mo;(2a); W(3a)], [Re(CO)4Br(5msalmsh)] (4a), [M(CO)5(5mafmsh)] [M=Cr;(1b), Mo;(2b); W(3b)], [Re(CO)4Br(5mafmsh)] (4b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO)6] (M=Cr, Mo, W) and [Re(CO)5Br] with N´-(2-Hydroxy-6-Methylbenzylidene) Methanesulfonohydrazide (5msalmsh) and 5-methyl-2-hydroxyacetophenonemethanesulfonylhydrazone (5mafmsh). The complexes have been characterized by elemental analysis, LC-MS, FT-IR, 1H NMR spectroscopy. Spectroscopic studies show that 5msalmsh and 5mafmsh behave monodentate ligand and coordinate via an imine N donor atom to the central metal atom in (1a)-(4a) and (1b)-(4b). © 2021 Slovensko Kemijsko Drustvo. All rights reserved.
Açıklama
Anahtar Kelimeler
Hydrazones, Metal carbonyls, Monodentate ligands, Photochemical reactions
Kaynak
Acta Chimica Slovenica
WoS Q Değeri
Scopus Q Değeri
N/A
Cilt
68
Sayı
2
