Vibrational spectroscopic analysis of some Hofmann-Td type complexes
Küçük Resim Yok
Tarih
2012
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
New Hofmann-Td type complexes in the form of Ni(4Chpy) 2M(CN)4 (M = Cd or Hg and 4chpy = 4-(3-cyclohexen-1-yl) pyridine) have been prepared and their FT-IR and FT-Raman spectra have been reported. The results suggest that present compounds are similar in structure to the Hofmann-Td type complexes, in which the M atom is tetrahedrally coordinated to the carbon atoms of the four cyanide groups, while the Ni atom is octahedrally surrounded by six nitrogen atoms, two of which are from 4chpy ligands which have been coordinated as a unidentate ligand and the rest are from cyanide groups. In this host structure, the M(CN)4 groups have been linked by the Ni(4chpy)2 moieties to form a three-dimensional network. © 2012 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
4-(3-Cyclohexen-1-yl)pyridine, Hofmann-Td type complexes, Vibrational spectra
Kaynak
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
WoS Q Değeri
Scopus Q Değeri
Q2
Cilt
97
