Physico-chemical properties of some polymer blended task specific novel S-(+)-2-3-dihydroxy-N, N, N-tributyl-propanaminiumtriflate and 1-(2-propoxy)-3-methylimdazolium-borohydride room temperature ionic liquids

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dc.contributor.authorRupini, B.
dc.contributor.authorKumar, Y.
dc.contributor.authorAkdag, H.
dc.contributor.authorVarlikli, C.
dc.contributor.authorShulga, Y. M.
dc.contributor.authorShulga, N. Y.
dc.contributor.authorKasana, V. K.
dc.date.accessioned2019-10-27T11:06:51Z
dc.date.available2019-10-27T11:06:51Z
dc.date.issued2017
dc.departmentEge Üniversitesien_US
dc.description.abstractTwo novel chiral ionic liquids S-(+)-2-3-dihydroxy-N, N, N-tributyl-propanaminiumtriflatc and 1-(2-propoxy)-3-methylimdazolium-borohydride have been prepared using conventional metathesis reaction. These ionic liquids have been subjected to solution cast method followed by ultrasonication to obtain the corresponding ionic liquid gel polymer electrolytes with poly (vinylidene fluoride-co-hexafiuoropropene) (PVDF-HFP), free-standing, rubbery, dimensionally stable films with a high degree of transparency have been obtained. Thermo-gravimetric analysis confirms that the intermediate solvent, acetone used for mixing PVDF-HFP polymer with ionic liquid is completely evaporated after gelation and drying process. Further thermal properties have been analyzed by differential scanning calorimetry. Scanning electron microscopy micrographs show the different surface morphology of the gel electrolytes according to nature of the ionic liquid. The structural information has been extracted by X-ray diffraction. The ionic conductivities of both polymer-ionic liquid blends are in the order of 10(-3) to 10(-5) cm(-1). Electrochemical stability window of these polymer electrolytes ranges from 4.0 to 5.0 V. Various physicochemical properties and fast ion conduction in the gel polymer membranes show their promising characteristics as electrolytes in different ionic devices.en_US
dc.description.sponsorshipUGCUniversity Grants Commission, India; Science and Engineering Research Board (SERB), Department of Science and Technology, Government of India [ECR/2016/001871]en_US
dc.description.sponsorshipThe authors gratefully acknowledge UGC for financial support under major research project scheme. The authors acknowledge the financial support received from the Science and Engineering Research Board (SERB), Department of Science and Technology, Government of India (sanction no. ECR/2016/001871) under the scheme Early Career Research Award.en_US
dc.identifier.endpage511en_US
dc.identifier.issn0019-5596
dc.identifier.issn0975-1041
dc.identifier.issn0019-5596en_US
dc.identifier.issn0975-1041en_US
dc.identifier.issue7en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage503en_US
dc.identifier.urihttps://hdl.handle.net/11454/31931
dc.identifier.volume55en_US
dc.identifier.wosWOS:000429395900006en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherNatl Inst Science Communication-Niscairen_US
dc.relation.ispartofIndian Journal of Pure & Applied Physicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectIonic liquidsen_US
dc.subjectPolymersen_US
dc.subjectBlendsen_US
dc.subjectIonic sizeen_US
dc.subjectIonic conductivityen_US
dc.titlePhysico-chemical properties of some polymer blended task specific novel S-(+)-2-3-dihydroxy-N, N, N-tributyl-propanaminiumtriflate and 1-(2-propoxy)-3-methylimdazolium-borohydride room temperature ionic liquidsen_US
dc.typeArticleen_US

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