Photophysical properties and electrochemistry of the N,N'-bis-n-butyl derivative of naphthalene diimide

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dc.contributor.authorPosokhov Y.
dc.contributor.authorAlp S.
dc.contributor.authorKöz B.
dc.contributor.authorDilgin Y.
dc.contributor.authorIçli S.
dc.date.accessioned2019-10-27T00:12:57Z
dc.date.available2019-10-27T00:12:57Z
dc.date.issued2004
dc.departmentEge Üniversitesien_US
dc.description.abstractThe spectral-luminescent properties and electrochemistry of the N,N'-bis-n-butyl derivative of naphthalene diimide were studied. The main photophysical parameters (quantum yield, rate constants of fluorescence and of non-radiative deactivation and fluorescence lifetime) were determined. The LUMO value (-3.51 eV) was determined by cyclic voltammetry. The N,N'-bis-n- butyl derivative of naphthalene diimide (BBND) shows 2 reversible reduction steps (-1.19 V and -1.75 V vs. Ferrocene) in chloroform. Quenching the fluorescence emissions of aromatic donor molecules in acetonitrile revealed the electron acceptor ability of the studied naphthalene diimide derivative. It has been found that, in contrast to perylene diimide derivatives, which form ?-electron donor-acceptor complexes with aromatic donor molecules of naphthalene, phenanthrene, pyrene and perylene, BBND does not form ?-electron-donor acceptor complexes with aromatic donor molecules.en_US
dc.identifier.endpage424en_US
dc.identifier.issn1300-0527
dc.identifier.issue4en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage415en_US
dc.identifier.urihttps://hdl.handle.net/11454/22403
dc.identifier.volume28en_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakTR-Dizinen_US
dc.language.isoenen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCyclic voltammetryen_US
dc.subjectN,N'-bis-n-butyl derivative of naphthalene diimideen_US
dc.subjectSpectral-luminescent propertiesen_US
dc.titlePhotophysical properties and electrochemistry of the N,N'-bis-n-butyl derivative of naphthalene diimideen_US
dc.typeArticleen_US

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